CANBYITE, A NEW MINERAL OCCURRENCE

A. C. HAWKINS and EARL V. SHANNON, Rochester, N. Y., and Washington D.C.

OCCURRENCE.

     Some thirty-five or forty years ago, when the Brandywine Quarry at Wilmington, Delaware, was in operation, Mr. Fred Hilbiber, then living in that city, discovered in this quarry the minerals here described. The quarry is located a quarter mile northwest of the Baltimore and Ohio Railroad bridge on Brandywine Creek. It is at present used as a storage yard adjacent to a leather manufacturing plant.

     The country rock is a gabbro, containing numerous quartz stringers and masses due to the effects of intrusive granite, and showing the minerals enumerated below. The minerals associated with the canbyite are as follows:

Bornite: pure masses, iridescent, weighing altogether several pounds.
Chalcopyrite: alone, and associated with bornite and pyrite.
Chalcocite: associated with garnet and hisingerite.
Pyrrhotite: narrow stringers associated with other sulphides.
Pyrite: brilliant simple cubes, 1 to 3 mm. in diameter.
Marcasite: coating surfaces of the rock, decomposing rapidly on exposure.
Garnet: fibrous crystalline crusts associated with hisingerite.
Apatite: bright crystals of a dark olive green color, showing prism, unit pyramid, and base; somewhat twisted and distorted by rock movements; embedded in quartz. Largest crystal observed, 2 X 5 cm.

Quartz: small crystals on gabbro, associated with calcite and stilbite.
Calcite: white crystals, about 3 X 5 mm. in size, terminated by r(l01), showing also prominently M(401) with a steep scalenohedron near (312). Also small unit rhombohedrons.

Chabazite: well formed crystals, the largest observed being 0.8 cm. in diameter. Colors, dark olive green, salmon, dark brown to light brown.

Natrolite: white and delicately acicular. Complete radiations, 2.2 cm. in diameter, crusts and veins. Associated with calcite, bornite and chalcopyrite, as are the other zeolites, which rest upon the sulphides.

Stilbite: radiations 1.3 cm. in diameter, single crystals and sheaves 0.5 cm. in size, drusy surfaces; colors, gray-green, salmon, orange-yellow to white.

Laumontite: opaque, cream-colored crystals 0.5 cm. long, on gabbro. Sharp free crystals showing prism and base, which are today in a good state of preservation.

Epidesmine: sheaf like rosettes 1 mm. in diameter, composed of colorless, transparent crystals, associated with calcite and natrolite.

Hisingerite: associated with canbyite, garnet, and sulphides.

     The optical properties of the epidesmine correspond closely with those given for this mineral in E. S. Larsen's Tables; many of the associated minerals, however, are filled with microscopic inclusions of rectangular or rod-like shapes and brown color, which are inferred to be hisingerite, and which may be responsible for the abnormal refractive indices, particularly the low alpha index values, shown by the minerals at this locality.

ANALYSIS AND OPTICAL PROPERTIES.

     The analysis indicates that the mineral is essentially a hydrated ferric silicate. While its composition can be practically duplicated by several published analyses of hisingerite, the present material is completely crystalline with definite optical properties, while hisingerite is a typically amorphous mineral and is always isotropic optically, or, at most, contains only rare, isolated and very minute birefracting grains. For this reason, and in consideration of several exhaustive treatments of the several groups of ferric silicate minerals which are awaiting publication, it seems most logical and less confusing to designate the present mineral by a distinct name. The name proposed is canbyite, in honor of the founder of the Natural History Society of Delaware, thru the courtesy of which society this mineral was made available for study.

     Canbyite is thus a crystalline compound corresponding to the amorphous hisingerite, altho it seems improbable that it is the only crystalline ferric silicate corresponding in composition to the hisingerite group.

     The canbyite occurs as a constituent of crusts which rest on a peculiar coarsely crystalline, translucent quartz having a bluish green color and greasy luster. The quartz contains scattered rhombic crystals of grayish feldspar, up to 2 cm. in diameter, crystals of pyroxene, and masses of chalcopyrite. The canbyite forms a platy dark brown layer from 1 to 2 mm. in thickness next to the quartz. This is immediately overlain by a fine columnar layer of garnet, the minute columns of which stand perpendicular and terminate above in a minute druse of ill-defined crystals. The garnet is transparent and pale greenish brown under the microscope. It is completely isotropic with an index of refraction above 1.82. Above the garnet there is a layer from 1 to 10 mm., in thickness of sulphides, mainly chalcopyrite and chalcocite upon which rest bright cubes of pyrite. The pyrite crystals are overlain by a thick layer of amorphous hisingerite which was originally botryoidal but has been filled completely with minute contraction cracks. The hisingerite is clear golden brown under the microscope and is isotropic. Its index of refraction is variable, but the majority of the grains range between 1.45 and 1.47. A partial analysis of the hisingerite, made on only 0.0517 gram of material gave the following results:

ANALYSIS OF HISINGERITE